Revealing thermal runaway routes in lithium-sulfur batteries

EurekAlert  March 14, 2022
Researchers in China investigated the thermal runaway behavior of Li-S pouch cells from the materials level and found that the thermal runaway route starts from cathode-induced reactions and then gets accelerated by reactions from the anode. The solvent vaporization was verified to dominate pressure building up during thermal runaway. Li-S batteries employing varied electrolytes with different thermal stabilities, even inorganic all solid-state electrolytes, all undergo rapid thermal runaway at a narrow temperature range due to the intrinsic thermal features of the sulfur cathode and Li metal anode sublimating, melting, and cross-reacting at high temperatures. According to the researchers their work depicting thermal runaway routes will shed fresh lights on the way forward for building next-generation Li-S battery with enhanced safety performance…read more. TECHNICAL ARTICLE 

Graphical abstract. Credit: Joule, March 14, 2022 

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