Phys.org  October 19, 2022 In many materials the ferroelectric behavior is suppressed at the few-nanometer scale. A team of researchers in the US (UC Berkeley, State University of Pennsylvania, Argonne National Laboratory, Lawrence Berkeley National Laboratory) found that ferroelectricity emerges in zirconium dioxide when it is grown extremely thin, approximately 1-2 nanometers in thickness. Notably, the ferroelectric behavior continues to its near-atomic-scale thickness limit of roughly half a nanometer. This approach to exploit three-dimensional centrosymmetric materials deposited down to the two-dimensional thickness limit, particularly within this model fluorite-structure system that possesses unconventional ferroelectric size effects, offers substantial promise for electronics, […]