Hidden distortions trigger promising thermoelectric property

Science Daily  May 9, 2022 Conventional structure transitions occur from a low symmetry state to a higher symmetry state upon warming. An international team of researchers (USA – Northwestern University, Brookhaven National Laboratory, Germany) found an unexpected local symmetry breaking in the tetragonal diamondoid compound silver gallium telluride. Upon warming, it evolved continuously from an undistorted ground state to a locally distorted state while retaining average crystallographic symmetry. This is a rare phenomenon previously referred to as emphanisis. The distorted state, caused by the weak orbital hybridization of tetrahedral Ag atoms, resulted in their displacement of the tetrahedron center and […]