New class of 2D material displays stable charge density wave at room temperature

Phys.org  March 1, 2024 Charge density waves are emergent quantum states that spontaneously reduce crystal symmetry, drive metal-insulator transitions, and precede superconductivity. In low-dimensions, distinct quantum states arise, however, thermal fluctuations and external disorder destroy long-range order. A team of researchers in the US (University of Michigan, Harvard University) has stabilized ordered 2D charge density waves through endotaxial synthesis of confined monolayers of 1T-TaS2. Specifically, an ordered incommensurate charge density wave (oIC-CDW) was realized in 2D with dramatically enhanced amplitude and resistivity. By enhancing CDW order, the hexatic nature of charge density waves became observable. Upon heating via in-situ TEM, […]

Ringing an electronic wave: Elusive massive phason observed in a charge density wave

Phys.org  March 9, 2023 The lowest-lying fundamental excitation of an incommensurate charge-density-wave material is believed to be a massless phason—a collective modulation of the phase of the charge-density-wave order parameter. However, long-range Coulomb interactions should push the phason energy up to the plasma energy of the charge-density-wave condensate, resulting in a massive phason and fully gapped spectrum. A team of researchers in the US (University of Illinois, SLAC National Accelerator Laboratory) used time-domain terahertz emission spectroscopy, to investigate this issue in (TaSe4)2I, a quasi-one-dimensional charge-density-wave insulator. On transient photoexcitation at low temperatures, they found the material strikingly emits coherent, narrowband […]