Phys.org  July 13, 2021 Oxide-based cathode materials are key components of secondary batteries. Problems originating from the lattice oxygen instability in oxide-based intercalation cathodes are widely reported, such as capacity degradation, gas generation, and thermal runaway, highlighting the importance of deep insights into the critical factors for lattice oxygen stability. Researchers in Japan Investigated the lattice oxygen stability in layered rock-salt LiNi1/3Co1/3Mn1/3O2−δ with a focus on oxygen release behavior and relevant changes in crystal and electronic structures. Release of lattice oxygen facilitates cation mixing, transition metal slab expansion, and Li slab contraction, thus deteriorating the layered structure. In the beginning […]