Phys.org  July 24. 2023 Researchers in China introduced platinum–rare earth metal-based alloy catalyst, Pt2Gd, to reveal the role of spin configurations in the catalytic activity of materials. The catalyst exhibited a unique intrinsic spin reconfiguration because of interactions between the Gd-4f and Pt-5d orbitals. The adsorption and desorption of the oxygen species were optimized by modifying the spin symmetry and electronic structures of the material for increased oxygen reduction reaction (ORR) efficiency. The Pt2Gd alloy exhibited a half-wave potential, and a superior mass activity, and higher durability than conventional Pt/C catalysts. Theoretical calculations have proved that the spin shielding effect […]