Nanowerk April 7, 2024 Magnetic field effects on electrocatalysis have recently gained attention due to the substantial enhancement of the oxygen evolution reaction (OER) on ferromagnetic catalysts. An international team of researchers (Switzerland, Argentina) used a specifically designed magneto-electrochemical system and non-magnetic electrodes to quantify magnetic field effects. They found marginal enhancement in reactions with high reactant availability, such as the OER, whereas substantial boosts exceeding 50% were observed in diffusion limited reactions, exemplified by the oxygen reduction reaction (ORR). According to the researchers their results advanced the fundamental understanding of magnetic fields in electrocatalysis and unveil new prospects for […]
Tag Archives: Electrocatalysis
Microscopic transformations of electrocatalyst surfaces
Nanowerk August 18, 2023 Potentiodynamic methods that induce structural changes in Cu catalysts for the electrochemical reduction of CO2 (CO2RR) have been identified as a promising strategy for steering the catalyst selectivity towards the generation of multi-carbon products. In the current approaches, active species are created via a sequential Cu oxidation–reduction process. Researchers in Germany have shown that low-coordinated Cu surface species form spontaneously near the onset of CO2 electrocatalytic reduction. This process started by CO-induced Cu nanocluster formation in the initial stages of the reaction, led to irreversible surface restructuring that persisted over a wide potential range. On subsequent […]
Device makes hydrogen from sunlight with record efficiency
Science Daily July 20, 2023 An international team of researchers (USA – Rice University, National Renewable Energy Laboratory, Lawrence Berkeley National Laboratory, Germany, France) designed and fabricated a conductive adhesive-barrier (CAB) that translates >99% of photoelectric power to chemical reactions. The CAB enabled halide perovskite-based photoelectrochemical cells with two different architectures that exhibited record STH efficiencies. The first, a co-planar photocathode-photoanode architecture, achieved an STH efficiency of 13.4% and 16.3 h to t60, solely limited by the hygroscopic hole transport layer in the n-i-p device. The second was formed using a monolithic stacked silicon-perovskite tandem, with a peak STH efficiency of […]
New, highly stable catalyst may help turn water into fuel
Science Daily September 28, 2018 Much of the previous work was performed with electrolyzers made from just two elements — one metal and oxygen. A team of researchers in the US (University of Illinois, Argonne National Laboratory) developed a porous material — a pyrochlore oxide of yttrium ruthenate which was more porous and had a new crystalline structure. As a porous structure is highly desirable when it comes electrocatalysts, the new materials could split water molecules at a higher rate than the current industry standard…read more. TECHNICAL ARTICLE