Phys.org December 20, 2024 Although porous structures should favor colonization by microorganisms, they have not yet been exploited as abiotic scaffolds for the development of living materials. Researchers in Switzerland developed porous ceramics that are colonized by bacteria to form an engineered living material with self-regulated and genetically programmable carbon capture and gas-sensing functionalities. The carbon capture capability was achieved using wild-type photosynthetic cyanobacteria, whereas the gas-sensing function was generated utilizing genetically engineered E. coli. Hierarchical porous clay was used as a ceramic scaffold and evaluated in terms of bacterial growth, water uptake, and mechanical properties. Using state-of-the-art chemical analysis […]
Tag Archives: Carbon capture
Capturing carbon from the air just got easier
Nanowerk October 24, 2024 The development of a durable material with high capacity, fast kinetics and low regeneration temperature for CO2 capture, especially from the intricate and dynamic atmosphere, is still lacking. An international team of researchers (USA – University of California, Saudi Arabia, Germany) synthesized a porous, crystalline covalent organic framework (COF) with olefin linkages structurally characterized and post-synthetically modified by the covalent attachment of amine initiators for producing polyamines within the pores. The COF could capture CO2 from open air with a capacity of 0.96 mmol g–1 under dry conditions and 2.05 mmol g–1 under 50% relative humidity, both from 400 ppm CO2. […]
Scientists discover molecules that store much of the carbon in space
MIT News October 24, 2024 Polycyclic aromatic hydrocarbons (PAHs) are organic molecules containing adjacent aromatic rings. Infrared emission bands show that PAHs are abundant in space, but only a few specific PAHs have been detected in the interstellar medium. An international team of researchers (USA – MIT, University of Michigan, Worcester State University, NASA Goddard Space Flight Center, Harvard Smithsonian, National Radio Astronomy Observatory, Virginia Military Institute, University of Virginia, Canada) detected 1-cyanopyrene, a cyano-substituted derivative of the related four-ring PAH pyrene, in radio observations of the dense cloud TMC-1. They estimated that pyrene contains up to 0.1% of the […]
Carbon dioxide, the main culprit of global warming, reborn as an antioxidant substance
Phys.org May 24, 2024 Microbial CO2 electroreduction (mCO2ER) offers a promising approach for producing high value multicarbon reductants from CO2 by combining CO2 fixing microorganisms with conducting materials. The solubility and availability of CO2 in an aqueous electrolyte pose significant limitations in this system. A team of researchers in South Korea demonstrated the efficient production of long-chain multicarbon reductants within a wet amine-based catholyte medium during mCO2ER. Optimizing the concentration of the biocompatible CO2 absorbent, monoethanolamine (MEA) led to enhanced CO2 fixation in the electroautotroph bacteria. MEA in the catholyte medium redirected the carbon flux towards carotenoid biosynthesis during mCO2ER. […]
Carbon-capture batteries developed to store renewable energy, help climate
Science Daily May 15, 2024 To investigate the deactivation and reactivation mechanisms of the aqueous Na–CO2 battery during extended cycling, researchers at Oak Ridge National Laboratory designed the cathode to include non-precious intermetallic catalysts. As the cell underwent repeated cycles, the voltage polarization during discharge progressively rose, eventually led to the cell’s deactivation and formation of decomposition products clogging the electrode surface. Results obtained from comprehensive characterization techniques provided insight into the decomposition products. They showed an electrochemical approach for regeneration of the aqueous cells. According to the researchers their findings provide a path toward creating long-duration systems with self-healing […]
New catalyst transforms carbon dioxide into sustainable byproduct
Science Daily May 3, 2023 About 90% of the acetic acid market is for feedstock in the manufacture of paints, coatings, adhesives, and other products. Production at this scale is primarily derived from methanol, which comes from fossil fuels. An international team of researchers (China, Canada, New Zealand, USA – Northwestern University) has created acetic acid out of carbon monoxide derived from captured carbon. Their process consisted of capturing CO2 and passing it through an electrolyzer where it reacted with water and electrons to form carbon monoxide. Gaseous CO was then passed through a second electrolyzer, where another catalyst transformed […]
Stripping carbon from the atmosphere might be needed to avoid dangerous warming—but it’s a deeply uncertain prospect
Phys.org November 25, 2022 The target to limit global warming to 1.5℃ this century remains but it is unlikely we’ll meet it. Attention is turning to other options for climate action, including large-scale carbon removal. Proponents argue carbon removal is required at a massive scale to avoid dangerous warming. However, successfully stripping carbon from the atmosphere at the scale our planet requires is a deeply uncertain prospect. The IPCC said in a report this year that large-scale deployment of carbon dioxide removal was “unavoidable” if the world is to reach net-zero greenhouse gas emissions. According to the IPCC report in […]
Diazotrophs are overlooked contributors to carbon and nitrogen export to the deep ocean
Phys.org October 17, 2022 Diazotrophs are widespread microorganisms that alleviate nitrogen limitation in 60% of our oceans, thereby regulating marine productivity. Yet, the group-specific contribution of diazotrophs to organic matter export has not been quantified. An international team of researchers (France, Israel, Spain) examined the fate of five groups of globally distributed diazotrophs by using an original combination of mesopelagic particle sampling devices across the subtropical South Pacific Ocean. They demonstrated that cyanobacterial and non-cyanobacterial diazotrophs are exported down to 1000 m depth. Phycoerythrin-containing UCYN-B and UCYN-C-like cells were recurrently found embedded in large organic aggregates or organized into clusters of […]
A simple, cheap material for carbon capture, perhaps from tailpipes
Science Daily August 5, 2022 A team of researchers in the US (UC Berkely, Stanford University, Texas A&M) has demonstrated new sustainable, solid-state, polyamine-appended, cyanuric acid–stabilized melamine nano porous networks (MNNs) via dynamic combinatorial chemistry (DCC) at the kilogram scale toward effective and high-capacity carbon dioxide capture. Polyamine-appended MNNs reaction mechanisms with carbon dioxide were elucidated with double-level DCC where two-dimensional heteronuclear chemical shift correlation nuclear magnetic resonance spectroscopy was performed to demonstrate the interatomic interactions. They distinguished ammonium carbamate pairs and a mix of ammonium carbamate and carbamic acid during carbon dioxide chemisorption. The coordination of polyamine and cyanuric […]
Low-cost battery-like device absorbs CO2 emissions while it charges
Science Daily May 19, 2022 The most advanced carbon capture technologies currently require large amounts of energy and they are expensive. Researchers in the UK have designed a supercapacitor that consists of two electrodes of positive and negative charge. They found that alternating from a negative to a positive voltage improved the supercapacitor’s ability to capture carbon. When the electrodes become charged, the negative plate draws in the CO2 gas, while ignoring other emissions, such as oxygen, nitrogen, and water. Using this method, the supercapacitor both captures carbon and stores energy. They have developed a technique to understand the mechanism […]