Nanowerk October 20, 2021 To better understand electronic and magnetic properties and understanding the mechanisms that govern the interactions at the interface an international team of researchers (Germany, Austria, Switzerland, Italy) coupled nickel-porphyrin with copper. Using theoretical and experimental spectro-microscopy approach they showed that the charge transfer occurring at the interface between nickel tetraphenyl porphyrins and copper changes both spin and oxidation states of the Ni ion. The chemically active Ni(I), even in a buried multilayer system, can be functionalized with nitrogen dioxide, allowing a selective tuning of the electronic properties of the Ni center that is switched to a […]
Category Archives: Materials science
New type of magnetism unveiled in an iconic material
Phys.org October 5, 2021 Using low-energy muon spin spectroscopy an international team of researchers (Italy, Germany, UK, Israel, South Korea, Japan) discovered the existence of surface magnetism in Sr2RuO4 in its normal state. They detected static weak dipolar fields yet manifesting at an onset temperature higher than 50 K. They ascribed this unconventional magnetism to orbital loop currents forming at the reconstructed Sr2RuO4 surface. The results confirm that physical properties can be dramatically modified at a complex material surface and at interfaces within thin film heterostructures, and these modifications can be exploited for discovering new science for basic and applied research […]
Smuggling light through opaque materials
Nanowerk October 5, 2021 Chalcogenide glasses have long been constrained to the near- and mid-infrared with respect to their applications in photonics because they strongly absorb wavelengths of light in the visible and ultraviolet parts of electromagnetic spectrum. An international team of researchers (USA – Duke University, US Naval Research Laboratory, industry, university of Pennsylvania, Aviation and Missile Center, Aviation and Missile Center, US Army, Italy) has experimentally demonstrated and reported near-infrared to ultraviolet frequency conversion in an As2S3-based metasurface, enabled by a phase locking mechanism between the pump and the inhomogeneous portion of the third harmonic signal. Due to […]
Physicists make square droplets and liquid lattices
Nanowerk September 15, 2021 To study if the non-equilibrium structures can be controlled or be useful researchers in Finland subjected combinations of oils with different dielectric constants and conductivities to an electric field. When an electric field turned on over the mixture, electrical charge accumulated at the interface between the oils shearing the interface out of thermodynamic equilibrium. The liquids were confined into a thin, nearly two-dimensional sheet taking various droplets and patterns. The droplets could be made into squares and hexagons with straight sides. The two liquids could be also made to form into interconnected lattices, grid patterns that […]
Just by changing its shape, scientists show they can alter material properties
Nanowerk September 13, 2021 An international team of researchers (USA – Argonne National Laboratory, University of Chicago, Israel) explored confined transport using a patterned structure in titania films, with feature sizes of 11–20 nm. They described how confinement changes the competing charge transport mechanisms, the patterned antidot array leads to displacement fields and confines the charge density that results in modified and emergent electron transport with an increase in conductivity. This emergent behavior can be described by considering electron interference effects. Characterization of the charge transport with electron holography and impedance spectroscopy, and through comparison with modeling, showed that nanoscale […]
Researchers reveal a novel metal where electrons flow with fluid-like dynamics
Phys.org September 6, 2021 An international team of researchers (USA -Boston College, Florida State University, UT Dallas, Switzerland) found that a strong interaction between electrons and phonons alters the transport of electrons from the diffusive, or particle-like, to hydrodynamic, or fluid-like, regime in a synthesis of Niobium and Germanium (NbGe2). Electrical resistivity measurements showed a higher-than-expected mass for electrons, and X-ray diffraction revealed the crystal structure of the material. The mass of electrons in all trajectories was three times larger than the expected value. The strong electron-phonon interaction was responsible for the heavy electron behavior. In future work the team […]
Researchers use organic semiconductor nanotubes to create new electrochemical actuator
Phys.org September 3, 2021 To improve the movement and response time for electrochemical actuator devices that operate in liquid a team of researchers at the University of Houston has developed electrochemical actuator that uses specialized organic semiconductor nanotubes (OSNTs). The device demonstrated excellent performance, low power consumption/strain, a large deformation, fast response, and excellent actuation stability. The enormous effective surface area of the nanotubular structure which facilitates the ion transport and accumulation results in high electroactivity and durability. The work provides new opportunities for next-generation actuators that can be utilized in artificial muscles and biomedical devices…read more. TECHNICAL ARTICLE
In a first, scientists capture a ‘quantum tug’ between neighboring water molecules
Phys.org August 25, 2021 An accurate description of the ultrafast vibrational motion of water molecules is essential for understanding the nature of hydrogen bonds and many solution-phase chemical reactions. An international team of researchers (USA – SLAC National Accelerator Laboratory, UC Davis, University of Nebraska, Stanford University, Sweden) measured the ultrafast structural response to the excitation of the OH stretching vibration in liquid water with femtosecond temporal and atomic spatial resolution using liquid ultrafast electron scattering. They observed a transient hydrogen bond contraction of roughly 0.04 Å on a timescale of 80 femtoseconds, followed by a thermalization on a timescale of […]
Lightweight composite material inspects itself: Changes in color indicate deformations
Science Daily August 23, 2021 An international team of researchers (Switzerland, UK) developed a new type of laminate that changes color as soon as the material is deformed. The laminate is composed of alternating layers of a plastic polymer and artificial nacre or mother-of-pearl and is modelled on the biological example of the mussel shell. It consists of glass platelets arranged in parallel, which are compacted, sintered, and solidified using a polymeric resin making it extremely hard and break-resistant. The second layer consists of a polymer and an indicator molecule synthesised specifically for this application. The molecule is activated as […]
Scientists Discover How to Make Glass So Hard, It Can Even Scratch Diamond
Science Alert August 13, 2021 An international team of researchers (China, Sweden, USA – Harvard university, Germany, Russia) has discovered the critical proportion of crystallized and amorphous carbon needed to create a glass with remarkable properties that won’t weaken under intense pressure. By subjecting spheres of carbon atoms to intense pressure and baking at temperatures between 1,000 and 1,200 degrees Celsius they obtained glassy materials dubbed AM – I, II and III. After tests they mapped the way the atoms bonded with one another, showing they all operated as a semiconductor on a level comparable with amorphous silicon. After Vickers […]