Nanowerk October 20, 2021
To better understand electronic and magnetic properties and understanding the mechanisms that govern the interactions at the interface an international team of researchers (Germany, Austria, Switzerland, Italy) coupled nickel-porphyrin with copper. Using theoretical and experimental spectro-microscopy approach they showed that the charge transfer occurring at the interface between nickel tetraphenyl porphyrins and copper changes both spin and oxidation states of the Ni ion. The chemically active Ni(I), even in a buried multilayer system, can be functionalized with nitrogen dioxide, allowing a selective tuning of the electronic properties of the Ni center that is switched to a [Ni(II), S = 1] state. While Ni acts as a reversible spin switch, it is found that the electronic structure of the macrocycle backbone, where the frontier orbitals are mainly localized, remains unaffected. These findings pave the way for using the present porphyrin-based system as a platform for the realization of multifunctional devices where the magnetism and the optical/transport properties can be controlled simultaneously by independent stimuli…read more. Open Access TECHNICAL ARTICLEÂ
Schematic representation of the behavior of the NiTPP/Cu(100) interface. Credit: Small, 12 October 2021Â