Sustainable batteries roadmap to 2030 and beyond

Nanowerk  February 9, 2022 A team of EU researchers has developed a roadmap that presents the research ideas proposed by BATTERY 2030+,  the European large-scale research initiative for future battery chemistries. A “chemistry-neutral” roadmap to advance battery research is outlined with a time horizon of more than ten years. The roadmap is centered around six themes: 1) accelerated materials discovery platform, 2) battery interface genome, with the integration of smart functionalities such as 3) sensing and 4) self-healing processes. Beyond chemistry related aspects also include crosscutting research regarding 5) manufacturability and 6) recyclability. The roadmap should be seen as an […]

Power at sea: Towards high-performance seawater batteries

Science Daily  January 31, 2022 Despite the many potential applications of seawater batteries (SWBs), the limited performance of available materials has hindered their commercialization. Researchers in South Korea have developed a process called ‘plasma in liquid,’ which involves preparing a mixture of precursors containing carbon, N, and S and discharging plasma into the solution resulting in a material with high doping levels of N and S with a structural backbone of carbon black. Experimentally they have confirmed that the material showed great potential for SWBs. The co-doped anode material exhibited remarkable electrochemical performance in SWBs, with a cycling life of […]

Development of a lithium-air battery with an energy density over 500 wh/kg

Science Daily  January 20, 2022 Lithium–air batteries (LABs) are potential candidates for next-generation rechargeable batteries because of their extremely high theoretical energy density. However, the reported values for the actual energy density of LABs are much lower than those for lithium batteries, mainly due to the excess amount of electrolyte in the cell. In the present review article, researchers in Japan estimated the practical energy density for the representative LABs reported in academia, and the critical factors for improving the energy density of LABs are summarized. The criteria for evaluating LABs in laboratory-based experiments are also proposed for accurately predicting […]

Light could boost performance of fuel cells, lithium batteries and other devices

Phys.org  January 14, 2022 In solid electrolytes the ionic conductivity is often markedly degraded by the fact that the ions get blocked at the crystallite grains boundaries. An international team of researchers (Spain, Germany, USA – MIT, Japan) has shown how light can be used to lower the barrier height that ions encounter at grain boundaries and enhance the flow of the ions by orders of magnitude by optimizing the system. They demonstrated the effect of light on the movement of oxygen ions through solid electrolyte composed of ceria and gadolinium. According to the researchers the process can be applied […]

Superabsorption unlocks key to next-generation quantum batteries

Phys.org  January 17, 2022 It is theoretically possible that the charging power of quantum batteries increases faster than the size of the battery which could allow new ways to speed charging. An international team of researchers (Australia, UK, Italy) built several wafer-like microcavities of different sizes containing organic semiconductor materials that store energy. They contained different numbers of organic molecules. Each was charged using a laser. Underlying the superabsorbing effect of the quantum batteries is the idea that all the molecules act collectively through quantum superposition. As the microcavity size increased and the number of molecules increased, the charging time […]

Molecular paddlewheels propel sodium ions through next-generation batteries

Science Daily  January 11, 2022 Identifying and controlling the pertinent phonon modes coupled most strongly with ionic conductivity, and assessing the role of anharmonicity, could pave the way for discovering and designing new solid electrolyted (SEs) via phonon engineering. A team of researchers in the US (Duke University, University of Louisville, Oak Ridge National Laboratory, Argonne National Laboratory) investigated phonons in sodium thiophosphate (Na3PS4) and their coupling to fast Na diffusion and identified that anharmonic soft modes at the Brillouin zone boundary of the anharmonically stabilized cubic phase constitute key phonon modes that control the Na diffusion process in Na3PS4. […]

Scientists reduce all-solid-state battery resistance by heating

Science Daily  January 7, 2022 The interface between the positive electrode and solid electrolyte in an all-solid state battery shows a large electrical resistance, and the resistance increases when the electrode surface is exposed to air, degrading the battery capacity and performance. Researchers in Japan demonstrated that drastic reduction of the resistance is achievable by annealing the entire battery cell. Exposing the LiCoO2 positive electrode surface to H2O vapor increases the resistance by more than 10 times (to greater than 136 Ω cm2). The magnitude can be reduced to the initial value (10.3 Ω cm2) by annealing the sample in […]

Revitalizing batteries by bringing ‘dead’ lithium back to life

Science Daily  January 4, 2022 Because i-Li loses electrical connection with the current collector, it has been considered electrochemically inactive or ‘dead’ in batteries. A team of researchers in the US (Stanford University, SLAC National Accelerator Laboratory) showed that i-Li is highly responsive to battery operations, owing to its dynamic polarization to the electric field in the electrolyte. Simultaneous Li deposition and dissolution occurs on two ends of the i-Li, leading to its spatial progression toward the cathode (anode) during charge (discharge). Through their results they showed that the progression rate of i-Li is mainly affected by its length, orientation, […]

MIT engineers produce the world’s longest flexible fiber battery

MIT News  December 20, 2021 Fibers as fundamental building blocks of fabrics and 3D-printed objects provide unique opportunities for developing pervasive multidimensional power systems. An international team of researchers (USA – MIT, US Army, South Korea) has developed a Li-ion battery fiber, fabricated using a thermal drawing method which occurs with simultaneous flows of multiple complex electroactive gels, particles, and polymers within protective flexible cladding. This top-down approach allows to produce fully functional and arbitrarily long lithium-ion fiber batteries. The continuous 140 m fiber battery demonstrated a discharge capacity of ∼123 mAh and discharge energy of ∼217 mWh. The scalability […]

Sodium-based material yields stable alternative to lithium-ion batteries

Science Daily  December 6, 2021 In earlier sodium batteries the anode would grow dendrites that can cause the battery to electrically short and even catch fire or explode. A team of researchers in the US (UT Austin, Los Alamos National Laboratory) developed a new anode material, sodium antimony telluride intermetallic — Na metal composite (NST-Na), by rolling a thin sheet of sodium metal onto an antimony telluride powder, folding it over on itself, and repeating many times. This process results in a very uniform distribution of sodium atoms that makes it less likely to form dendrites or surface corrosion than […]