Science Daily May 3, 2022 Polysulfide-air redox flow batteries demonstrated great potential for long-duration energy storage technologies that can be deployed at grid scale. However, the crossover of polysulfide is one significant challenge. Researchers in the UK have developed a stable and cost-effective alkaline-based hybrid polysulfide-air redox flow battery where a dual-membrane-structured flow cell design mitigates the sulfur crossover issue. Moreover, combining manganese/carbon catalyzed air electrodes with sulfidated Ni foam polysulfide electrodes, the redox flow battery achieves a maximum power density of 5.8 mW cm−2 at 50% state of charge and 55 °C. Compared with the best results obtained to date […]
Category Archives: Battery technology
Achieving higher performance with potassium ion battery
Phys.org April 14, 2022 Low temperature aqueous batteries (LT-ABs) have attracted extensive attention in recent years. However, they suffer from electrolyte freezing, slow ionic diffusion and sluggish interfacial redox kinetics at low temperature. In a review article researchers in China discussed the physicochemical properties of aqueous electrolytes in terms of phase diagram, ion diffusion and interfacial redox kinetics to guide the design of low temperature aqueous electrolytes (LT-AEs). They introduced the characteristics of equilibrium and non-equilibrium phase diagrams to analyze the antifreezing mechanisms and propose design strategies for LT-AEs. To understand and regulate the ion diffusion kinetics they reviewed the […]
Shapeable carbon fiber networks with hierarchical porous structure for high-performance Zn-I2 batteries
Nanowerk March 16, 2022 Although aqueous rechargeable zinc-iodine batteries (ZIBs) emerged as a promising energy storage alternative they suffer from the severe shuttle effect of polyiodide and poor reversibility, leading to the poor cycling lifetime and potential safety issues. Researchers in China found that the assembly of Al-based metal-organic frameworks (Al-MOFs) in the presence of polyacrylonitrile (PAN) via electrospinning technique enabled the formation of Al-MOF/PAN fibers. With the subsequent pyrolysis, the hierarchical porous carbon fibers with nitrogen doping (NPCNFs) are prepared for loading iodine. The confinement effect of the porous carbon network and the nitrogen doping, inhibits the shuttle effect […]
Development of stretchable and printable free-form lithium-ion batteries
Nanowerk March 25, 2022 Researchers in South Korea have developed a fully stretchable lithium-ion battery system using stretchable electrode. It acquires intrinsic stretchability and improved interfacial adhesion with the active materials via a functionalized physically cross-linked organogel as a stretchable binder and separator. The stretchable current collectors are fabricated in the form of nanocomposites consisting of a matrix with excellent barrier properties without swelling in organic electrolytes and nanostructure-controlled multimodal conductive fillers. They demonstrated several types of stretchable lithium-ion batteries that reliably operated under various stretch deformations with capacity and rate capability comparable with a nonstretchable batteries even under high […]
Revealing thermal runaway routes in lithium-sulfur batteries
EurekAlert March 14, 2022 Researchers in China investigated the thermal runaway behavior of Li-S pouch cells from the materials level and found that the thermal runaway route starts from cathode-induced reactions and then gets accelerated by reactions from the anode. The solvent vaporization was verified to dominate pressure building up during thermal runaway. Li-S batteries employing varied electrolytes with different thermal stabilities, even inorganic all solid-state electrolytes, all undergo rapid thermal runaway at a narrow temperature range due to the intrinsic thermal features of the sulfur cathode and Li metal anode sublimating, melting, and cross-reacting at high temperatures. According to […]
World’s smallest battery can power dust-sized computer
Nanowerk February 19, 2022 The size and adequate energy storage mismatch between microbatteries and microelectronics has emerged as a fundamental barrier against the take-off of tiny intelligent systems requiring power anytime anywhere. The on-chip self-assembly process known as micro-origami is capable of winding stacked thin films into Swiss-roll structures to reduce the footprint area, which exactly mimics the manufacture of the most successful full-sized batteries—cylinder batteries. In addition to discussing in detail the technical difficulties of reducing the size of on-chip microbatteries with various structures and potential solutions, researchers in Germany highlight the following two basic requirements for eventual integration […]
It’s in the air – battery discovery takes up the charge
Science Daily February 10, 2022 An international team of researchers (Australia, China, USA – Argonne National Laboratory) describe the details of an Li-O2 battery operated via a new quenching/mediating mechanism that relies on the direct chemical reactions between a versatile molecule and superoxide radical/Li2O2. The battery exhibits a 46-fold increase in discharge capacity, a low charge overpotential of 0.7 V, and an ultralong cycle life greater than 1400 cycles. Redox-active 2,2,6,6-tetramethyl-1-piperidinyloxy moieties bridged by a quenching-active perylene diimide backbone acts as a redox mediator to catalyze discharge/charge reactions and serves as a reusable superoxide quencher to chemically react with superoxide […]
Sustainable batteries roadmap to 2030 and beyond
Nanowerk February 9, 2022 A team of EU researchers has developed a roadmap that presents the research ideas proposed by BATTERY 2030+, the European large-scale research initiative for future battery chemistries. A “chemistry-neutral” roadmap to advance battery research is outlined with a time horizon of more than ten years. The roadmap is centered around six themes: 1) accelerated materials discovery platform, 2) battery interface genome, with the integration of smart functionalities such as 3) sensing and 4) self-healing processes. Beyond chemistry related aspects also include crosscutting research regarding 5) manufacturability and 6) recyclability. The roadmap should be seen as an […]
Power at sea: Towards high-performance seawater batteries
Science Daily January 31, 2022 Despite the many potential applications of seawater batteries (SWBs), the limited performance of available materials has hindered their commercialization. Researchers in South Korea have developed a process called ‘plasma in liquid,’ which involves preparing a mixture of precursors containing carbon, N, and S and discharging plasma into the solution resulting in a material with high doping levels of N and S with a structural backbone of carbon black. Experimentally they have confirmed that the material showed great potential for SWBs. The co-doped anode material exhibited remarkable electrochemical performance in SWBs, with a cycling life of […]
Development of a lithium-air battery with an energy density over 500 wh/kg
Science Daily January 20, 2022 Lithium–air batteries (LABs) are potential candidates for next-generation rechargeable batteries because of their extremely high theoretical energy density. However, the reported values for the actual energy density of LABs are much lower than those for lithium batteries, mainly due to the excess amount of electrolyte in the cell. In the present review article, researchers in Japan estimated the practical energy density for the representative LABs reported in academia, and the critical factors for improving the energy density of LABs are summarized. The criteria for evaluating LABs in laboratory-based experiments are also proposed for accurately predicting […]