Linking two solar technologies is a win-win for efficiency and stability

Nanowerk  September 5, 2023
Although metal halide perovskites have rapidly enabled a range of high-performance photovoltaic technologies, their catastrophic failure under reverse voltage bias poses a roadblock for their commercialization. An international team of researchers (Princeton University, Saudi Arabia) conducted a series of stress tests to compare the reverse-bias stability of perovskite single-junction, silicon single-junction, and monolithic perovskite/silicon tandem solar cells. They demonstrated that the tested perovskite/silicon tandem devices were considerably more resilient against reverse bias compared with perovskite single-junction devices. The origin of such improved stability stemmed from the low reverse-bias diode current of the silicon subcell. This translated to dropping most of the voltage over the silicon subcell, where such a favorable voltage distribution protects the perovskite subcell from reverse-bias-induced degradation. According to the researchers their results highlight that, compared with other perovskite technologies, monolithic perovskite/silicon tandems are at a higher technology readiness level in terms of tackling the reverse bias and partial shading challenges, which is a considerable advantage toward commercialization… read more. TECHNICAL ARTICLE 

Graphical abstract. Credit: Joule, September 05, 2023

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