Plumbing the depths of thermoelectrics in search of novel materials

Phys.org   September 18, 2023 Although historically the thermoelectric effect was first discovered in metals, state-of-the-art research focuses on semiconductors. An international team of researchers (Austria, Japan) discovered unprecedented thermoelectric performance in metals and realized ultrahigh power factors in binary nickel and gold alloys, more than twice larger than in any bulk material above room temperature. In metallic NixAu1–x alloys, large Seebeck coefficients originated from electron-hole selective scattering of Au s electrons into more localized Ni d states. This intrinsic energy filtering effect owing to the unique band structure yielded a strongly energy-dependent carrier mobility. While the metastable nature of the […]