Phys.org  July 31, 2023 The low thermal expansion of Fe–Ni Invar has long been associated with magnetism, but to date, the microscopic underpinnings of the Invar behaviour have eluded both theory and experiment. An international team of researchers (USA – Caltech, Boston College, Argonne National Laboratory, Israel) applied thermodynamic Maxwell relation to nuclear resonant X-ray scattering measurements of the phonon and magnetic entropies under pressure to obtain the separate phonon and magnetic contributions to thermal expansion. They found that the Invar behaviour stems from a competition between phonons and spins. In particular, the phonon contribution to thermal expansion cancelled the […]