Phys.org  June 15, 2022 It is a challenge to prepare large-sized single-crystal 2D carbon materials with moderate bandgaps to complement zero-bandgap graphene. Researchers in Chia prepared a single-crystal 2D carbon material, namely monolayer quasi-hexagonal-phase fullerene (C60) via an interlayer bonding cleavage strategy. In this monolayer polymeric C60, cluster cages of C60 are covalently bonded with each other in a plane, forming a regular topology that is distinct from that in conventional 2D materials. It exhibited high crystallinity and good thermodynamic stability, and the electronic band structure measurement revealed a transport bandgap of about 1.6 electronvolts. An asymmetric lattice structure endows monolayer […]