Phys.org  July 6, 2024 Although membranes based on a porous two-dimensional selective layer offer the potential to achieve exceptional performance to improve energy efficiency and reduce the cost for carbon capture, competitive sorption of CO2 with the potential to yield high permeance and selectivity has remained elusive. Researchers in Switzerland showed that a simple exposure of ammonia to oxidized single-layer graphene at room temperature incorporates pyridinic nitrogen at the pore edges. This led to a highly competitive but quantitatively reversible binding of CO2 with the pore. A combination of CO2/N2 separation factor and CO2 permeance from a stream containing 20 vol% […]