Engineers solve a mystery on the path to smaller, lighter batteries

MIT News  November 18, 2022 Whether dendrites are driven by mechanical failure or electrochemical degradation of solid electrolytes remains an open question. If internal mechanical forces drive failure, superimposing a compressive load that counters internal stress may mitigate dendrite penetration. A team of researchers in the US (MIT, Brown University) investigated this hypothesis by dynamically applying mechanical loads to growing dendrites in Li6.6La3Zr1.6Ta0.4O12 solid electrolytes. Operando microscopy revealed marked deflection in the dendrite growth trajectory at the onset of compressive loading. Sufficient loading the deflection averted cell failure. They quantified the impact of stack pressure and in-plane stresses on dendrite […]