Phys.org March 26, 2024 To understand the factors that promote bimetallic H–H coupling researchers at the University of North Carolina at Chapel Hill, USA, subjected molecular iridium catalysts to undergo photoelectrochemical dihydrogen (H2) evolution via a bimolecular mechanism. Covalently tethered diiridium catalysts evolved H2 from neutral water faster than monometallic catalysts, even at lower overpotential. The unexpected origin of this improvement was non-covalent supramolecular self-assembly into nanoscale aggregates that efficiently harvested light and form H–H bonds. Monometallic catalysts containing long-chain alkane substituents leveraged the self-assembly to evolve H2 from neutral water at low overpotential and with rates close to the […]
Tag Archives: Light harvesting
Harvesting light like nature does
Nanowerk May 15, 2021 Inspired by the formation of hierarchically structured natural biominerals (e.g., bone and tooth), various sequence-defined polymers have been synthesized and exploited for design and synthesis of functional hybrid materials. A team of researchers in the US (Pacific Northwest National Laboratory, Washington State University) created an altered protein-like structure, called a peptoid, and attached a precise silicate-based cage-like structure to one end of it. They found that, under the right conditions, they could induce these molecules to self-assemble into perfectly shaped crystals of 2D nanosheets. It has the programmability of a protein-like synthetic molecule with the complexity […]