Phys.org  March 18, 2024 Metal nanoclusters have emerged as NIR–emissive materials, but their room-temperature photoluminescence quantum yield (PLQY), especially in solution, is often low. Researchers in China studied the photophysics of Au22(tBuPhC≡C)18 (Au22) and its alloy counterpart Au16Cu6(tBuPhC≡C)18 (Au16Cu6) (where tBu is tert-butyl and Ph is phenyl) and found that copper doping suppressed the nonradiative decay and promoted intersystem crossing rate ~300-fold higher. According to the researchers their approach could enable the development of highly emissive metal cluster materials… read more. TECHNICAL ARTICLE