Phys.org  May 29, 2024 Thermal conductivity and elastic modulus are usually positively correlated in soft materials. A team of researchers in the US (North Carolina State University, Texas A&M University) have shown anomalous correlations of thermal conductivity and elastic modulus in 2D hybrid organic–inorganic perovskites (HOIP) by engineering the molecular interactions between organic cations. By replacing conventional alkyl–alkyl and aryl–aryl type organic interactions with mixed alkyl–aryl interactions, they observed an enhancement in elastic modulus with a reduction in thermal conductivity. The anomalous dependence provided a route to engineer thermal conductivity and elastic modulus independently and a guideline to search for […]