Phys.org  July 21, 2023 MOFs which possess a high degree of crystallinity and a large surface area with tunable inorganic nodes and organic linkers. The adsorption in MOFs changes the crystalline structure and elastic moduli. Thus, the coexistence of adsorbed/desorbed sites makes the host matrices elastically heterogeneous. To show the asymmetric role of elastic heterogeneity in the adsorption–desorption transition researchers in Japan constructed a minimal model incorporating adsorption-induced lattice expansion/contraction and an increase/decrease in the elastic moduli. They found that the transition was hindered by the entropic and energetic effects which become asymmetric in the adsorption process and desorption process, […]