Phys.org October 28, 2024 Researchers in Japan synthesized Fe-doped polyaniline (D-PANI) in which they observed diamagnetism at T < 24 K under a weak external magnetic field. D-PANI was air-stable and showed the Peierls transition, as its resistivity increased rapidly at low temperatures, behaving as an electromagnetic insulator. It showed high sensitivity to magnetic fields, with its diamagnetic character changing under a relatively low magnetic field at 4 K. Its resistivity remained almost constant at high temperatures, and the nearest neighbor electron hopping conduction. Polarons in D-PANI showed perfect diamagnetism at low temperatures. After purification, D-PANI contained C, N, O, […]
Tag Archives: Conducting polymers
Untwisting plastics for charging Internet-of-things devices
Nanowerk May 27, 2020 To use body heat to charge some types of micro-devices and sensors requires lightweight, non-toxic, wearable, and flexible thermoelectric generators. Researchers in Japan studied the thermoelectric properties of a highly conductive thiophene-based polymer, called PBTTT. They found that doping the polymer with a thin ion electrolyte gel improves conductivity and infiltrates the polymer successfully when a specific electric voltage is applied. Doping it with a critical amount of electrolyte untwists the highly twisted chain and creates links between its crystalline parts, improving electron conductivity. They are now looking into ways to optimize the thermoelectric performance of […]
Untwisting plastics for charging internet-of-things devices
Science Daily April 16, 2020 To use body heat to charge some types of micro-devices and sensors lightweight, non-toxic, wearable, and flexible thermoelectric generators are required. Japan studied the thermoelectric properties of highly conductive thiophene-based polymer, called PBTTT. They doped the polymer with a thin ion electrolyte gel, which is known to improve conductivity that infiltrates the polymer successfully when a specific electric voltage is applied. They found that, without the electrolyte gel, the PBTTT chain is highly twisted. Doping it with a critical amount of electrolyte untwists the chain and creates links between its crystalline parts, improving electron conductivity. […]