Phys.org March 6, 2024 Criegee intermediates are reactive intermediates that are implicated in transforming the composition of Earth’s troposphere and in the formation of secondary organic aerosol, impacting Earth’s radiation balance, air quality and human health. Direct identification of their signatures in the field are not available. An international team of researchers (USA – Argonne National Laboratory, NASA Jet Propulsion Laboratory, Sandia National Laboratory, Caltech, Princeton University, Princeton Plasma Physics Laboratory, UC Davis, UK, Turkey, Brazil, France) has identified sequences of masses consistent with the expected signatures of oligomerization of the CH2OO Criegee intermediate, a process implicated in ozonolysis-driven aerosol […]
Tag Archives: Atmospheric chemistry
Scientists discover a way Earth’s atmosphere cleans itself
Phys.org April 7, 2023 Hydroxyl radical (OH) is a key oxidant that triggers atmospheric oxidation chemistry in both gas and aqueous phases. The current understanding of its aqueous sources is mainly based on known bulk (photo) chemical processes, uptake from gaseous OH, or related to interfacial O3 and NO3 radical-driven chemistry. An international team of researchers (France, USA – UC Irvine, Israel) has provided experimental evidence that OH radicals are spontaneously produced at the air–water interface of aqueous droplets in the dark and the absence of known precursors, possibly due to the strong electric field that forms at such interfaces. […]