Scientists unlock reversible twisting of nanoscale materials

Nanowerk   September 13, 2023 Nanomaterials usually fail to twist into helical crystals. Considering the irreversibility of the previously studied twisting forces, the reverse process (untwisting) and retwisting areas more difficult to achieve. Researchers in China have reported a new reciprocal effect between molecular geometry and crystal structure which triggered a twisting-untwisting-retwisting cycle for tri-cobalt salicylate hydroxide hexahydrate. The twisting force stemmed from competition between the condensation reaction and stacking process, different from the previously reported twisting mechanisms. The resulting distinct nanohelices gave rise to unusual structure elasticity, as reflected in the reversible change of crystal lattice parameters and the mutual […]